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Accurate measurement of atmospheric reactive mercury (RM) presents analytical challenges due to its reactivity and ultra-trace concentrations. In the last decade, use of the University of Nevada, Reno – Reactive Mercury Active System (RMAS) for RM measurements has increased since it has been shown to be more accurate than the industry standard, the Tekran 2537/1130/1135 system. However, RMAS measurements also have limitations, including long time resolution and sampling biases associated with membranes used for RM sampling. We therefore investigated the use of higher sampling flow rates to reduce sampling time and tested alternative membrane materials using both ambient air sampling and controlled laboratory experiments with a gaseous oxidized mercury (GOM) calibrator. Results indicated that increasing the RMAS sampling flow had a negative impact on determined RM concentrations. RM concentrations at 2 L min−1 were 10% and 30–50% lower than at 1 L min−1 in spring/summer and winter, respectively. However, the chemical composition of RM captured on membranes was not impacted by the increased flow rate. Membranes currently used in the RMAS performed better than numerous alternatives with similar composition, retaining Hg more efficiently. Both ambient air sampling and laboratory experiments revealed that membranes designed to retain only particulate-bound mercury (PBM) also retained significant amounts of GOM. PBM membranes based on borosilicate glass designs retained more than 70% of GOM. 

There is much uncertainty regarding the sources of reactive mercury (RM) compounds and atmospheric chemistry driving their formation. This work focused on assessing the chemistry and potential sources of reactive mercury measured in Reno, Nevada, United States, using 1 year of data collected using Reactive Mercury Active System. In addition, ancillary meteorology and criteria air pollutant data, Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) analyses, and a generalized linear model were applied to better understand reactive mercury observations. During the year of sampling, a fire event impacted the sampling site, and gaseous elemental Hg and particulate-bound mercury concentrations increased, as did Hg^II-S compounds. Data collected on a peak above Reno showed that reactive mercury concentrations were higher at higher elevation, and compounds found in Reno were the same as those measured on the peak. HYSPLIT results demonstrated RM compounds were generated inside and outside of the basin housing Reno. Compounds were sourced from San Francisco, Sacramento, and Reno in the fall and winter, and from long-range transport and the marine boundary layer during the spring and summer. The generalized linear model produced correlations that could be explained; however, when applying the model to similar data collected at two other locations, the Reno model did not predict the observations, suggesting that sampling location chemistry and concentration cannot be generalized. 

Abstract We report the discovery of 15 exceptionally luminous 10 ≲z≲ 14 candidate galaxies discovered in the first 0.28 deg²of JWST/NIRCam imaging from the COSMOS-Web survey. These sources span rest-frame UV magnitudes of −20.5 >M_UV> −22, and thus constitute the most intrinsically luminousz≳ 10 candidates identified by JWST to date. Selected via NIRCam imaging, deep ground-based observations corroborate their detection and help significantly constrain their photometric redshifts. We analyze their spectral energy distributions using multiple open-source codes and evaluate the probability of low-redshift solutions; we conclude that 12/15 (80%) are likely genuinez≳ 10 sources and 3/15 (20%) likely low-redshift contaminants. Three of ourz∼ 12 candidates push the limits of early stellar mass assembly: they have estimated stellar masses ∼ 5 × 10⁹M_⊙, implying an effective stellar baryon fraction ofϵ_⋆∼ 0.2−0.5, whereϵ_⋆≡M_⋆/(f_bM_halo). The assembly of such stellar reservoirs is made possible due to rapid, burst-driven star formation on timescales < 100 Myr where the star formation rate may far outpace the growth of the underlying dark matter halos. This is supported by the similar volume densities inferred forM_⋆∼ 10¹⁰M_⊙galaxies relative toM_⋆∼ 10⁹M_⊙—both about 10⁻⁶Mpc⁻³—implying they live in halos of comparable mass. At such high redshifts, the duty cycle for starbursts would be of order unity, which could cause the observed change in the shape of the UV luminosity function from a double power law to a Schechter function atz≈ 8. Spectroscopic redshift confirmation and ensuing constraints of their masses will be critical to understand how, and if, such early massive galaxies push the limits of galaxy formation in the Lambda cold dark matter paradigm. 

Abstract The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy^1–4. However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality^5–9. Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6–2.8 μm in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement (‘metallicity’) of about 10–30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet’s terminator. 

Abstract Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems^1,2. Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based^3–5and high-resolution ground-based^6–8facilities. Here we report the medium-resolution (R ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref. ⁹), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO₂(28.5σ) and H₂O (21.5σ), and identify SO₂as the source of absorption at 4.1 μm (4.8σ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO₂, underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range¹⁰. 

Abstract Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy (for example, refs.^1,2) provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution and high precision, which, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST’s Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0–4.0 micrometres, exhibit minimal systematics and reveal well defined molecular absorption features in the planet’s spectrum. Specifically, we detect gaseous water in the atmosphere and place an upper limit on the abundance of methane. The otherwise prominent carbon dioxide feature at 2.8 micrometres is largely masked by water. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1–100-times solar (that is, an enrichment of elements heavier than helium relative to the Sun) and a substellar C/O ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation (for example, refs.^3,4,) or disequilibrium processes in the upper atmosphere (for example, refs.^5,6). 

Abstract Carbon dioxide (CO₂) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO₂is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’)^1–3, and thus the formation processes of the primary atmospheres of hot gas giants^4–6. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets^7–9. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO₂, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification^10–12. Here we present the detection of CO₂in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme^13,14. The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO₂absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO₂, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models.